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27 January, 14:03

Why are the electron affinities of the group 4a elements more negative than those of the group 5a elements?

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  1. 27 January, 17:33
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    The electron subshells in the atoms of group 5a elements discourage electron addition.

    This is because the subshells in the group 5a elements are already half-filled, which is a more stable electronic configuration that that which would be achieved if another electron was added.

    Meanwhile, group 4a elements' subshell becomes half-filled when an electron is added, making them somewhat stable. This means that they prefer electron addition.
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