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2 April, 13:33

Which substance has a coefficient of 2 when you balance the equation for this redox reaction? cu (s) + hno3 (aq) → cu (no3) 2 (aq) + no (g) + h2o (l) hno3 (aq) no (g) h2o (l) cu (s) ?

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  1. 2 April, 14:13
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    In this redox reaction, the Cu goes from oxidation state of (0) to (+2), therefore it oxidises. N in HNO₃ goes from oxidation state of (+5) to N in NO with oxidation state of (+2) and becomes reduced.

    Cu acts as the reducing reagent and HNO₃ is the oxidising agent.

    oxidation half reaction

    Cu - - - > Cu²⁺ + 2e - - 1)

    reduction half reaction

    4H⁺ + 3e + NO₃⁻ - - - > NO + 2H₂O - - 2)

    to balance the number of electrons, 1) x3 and 2) x2

    3Cu - - - > 3Cu²⁺ + 6e

    8H⁺ + 6e + 2NO₃⁻ - - - > 2NO + 4H₂O

    add the 2 equations

    3Cu + 8H⁺ + 2NO₃⁻ - - - > 3Cu²⁺ + 2NO + 4H₂O

    add 6 nitrate ions to both sides to add up to 8 and form acid with 8H⁺ ions

    3Cu + 8HNO₃ - - - > 3Cu (NO₃) ₂ + 2NO + 4H₂O

    Balanced equation for the redox reaction is as follows;

    3Cu (s) + 8HNO₃ (aq) → 3Cu (NO₃) ₂ (aq) + 2NO (g) + 4H₂O (l)

    NO has a coefficient of 2
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