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16 September, 20:23

Using the method of initial rates for the reaction a → b, if the initial concentration of a is doubled and the rate of reaction quadruples, what is the order of reaction with respect to a?

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  1. 16 September, 22:45
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    Answer is: reaction is second order with respect to a.

    This second order reaction is proportional to the square of the concentration of reactant a.

    rate of reaction = k[a]².

    k is second order rate constant and have unit M⁻¹·s⁻¹.

    Integrated rate law for this reaction: 1/[a] = 1 / [a] ₀ + kt.

    t is time in seconds ...
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