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30 March, 05:22

What is the molar solubility of fe (oh) 3 in pure water? (ksp for fe (oh) 3 is 4.0 x 10-38.)

a. 6.5 x 10-7 m

b. 4.5 x 10-10 m

c. 4.0 x 10-17 m

d. 2.0 x 10-10 m

e. 3.4 x 10-13 m?

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  1. 30 March, 07:24
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    A) Pure water (assume that the pH is 7.0 and remains constant).

    [OH-] = 10⁻⁷

    [Fe (3+) ] = 4.0x10⁻³⁸/[OH-]³ = 4.0x10⁻¹⁷ (M)

    That means the solubility is 4.0x10⁻¹⁷ mol/L.

    (B) A solution buffered at pH = 5.0.

    [OH-] = 10⁻⁹

    [Fe (3+) ] = 4.0x10⁻³⁸/[OH-]³ = 4.0x10⁻¹¹ (M)

    That means the solubility is 4.0x10⁻¹¹ mol/L.

    (C) A solution buffered at pH = 11.0.

    [OH-] = 10⁻³

    [Fe (3+) ] = 4.0x10⁻³⁸/[OH-]³ = 4.0x10⁻²⁹ (M)

    That means the solubility is 4.0x10⁻²⁹ mol/L.
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