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24 October, 05:06

At 1500°c the equilibrium constant for the reaction co (g) + 2h2 (g) ch3oh (g) has the value kp = 1.4 * 10-7. calculate? g° for this reaction at 1500°c.

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  1. 24 October, 07:31
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    To determine the standard gibbs free energy, we need an equation that would relate chemical equilibrium and the free energy. We derive this expression from the relationship:

    ΔG = ΔG° + RT ln Q

    When the system is at equilibrium G = 0 which means the system had reached the minimum free energy. At this state, the reaction quotient is equal to the equilibrium constant. So, the reaction reduce to

    0 = ΔG° + RT ln Kp

    ΔG° = - RT ln Kp

    We use this equation as follows:

    ΔG° = - RT ln Kp

    ΔG° = - 8.314 (1500 + 273.15) ln (1.4x10^-7)

    ΔG° = 232652.2047 J / mol

    The standard Gibbs Free Energy at 1500 degrees Celsius is 232652.2047 J / mol.
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