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7 February, 07:05

Calculate the energy required to ionize a ground state hydrogen atom. report your answer in kilojoules.

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  1. 7 February, 09:55
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    First we find for the wavelength of the photon released due to change in energy level. We use the Rydberg equation:

    1/ʎ = R [1/n1^2 - 1/n2^2]

    where,

    ʎ is the wavelength

    R is the rydbergs constant = 1.097*10^7 m^-1

    n1 is the 1st energy level = 1

    n2 is the higher energy level = infinity, so 1/n2 = 0

    Calculating for ʎ:

    1/ʎ = 1.097*10^7 m^-1 * [1/1^2 - 0]

    ʎ = 9.1158 x 10^-8 m

    Then calculate the energy using Plancks equation:

    E = hc/ʎ

    where,

    h is plancks constant = 6.626*10^-34 J s

    c is speed of light = 3x10^8 m/s

    E = (6.626*10^-34 J s * 3x10^8 m/s) / 9.1158 x 10^-8 m

    E = 2.18 x 10^-18 J = 2.18 x 10^-21 kJ

    This is still per atom, so multiply by Avogadros number = 6.022 x 10^23 atoms / mol:

    E = (2.18 x 10^-21 kJ / atom) * (6.022 x 10^23 atoms / mol)

    E = 1312 kJ/mol
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