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18 May, 12:53

A solution contains 0.115 mol h2o and an unknown number of moles of nacl. the vapor pressure of the solution at 30°c is 25.7 torr. the vapor pressure of pure water at 30° c is 31.8 torr. calculate the number of moles of nacl

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  1. 18 May, 14:03
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    According to Raoult's low:

    We will use this formula: Vp (Solution) = mole fraction of solvent * Vp (solvent)

    ∴ mole fraction of solvent = Vp (Solu) / Vp (Solv)

    when we have Vp (solu) = 25.7 torr & Vp (solv) = 31.8 torr

    So by substitution:

    ∴ mole fraction of solvent = 25.7 / 31.8 = 0.808

    when we assume the moles of solute NaCl = X

    and according to the mole fraction of solvent formula:

    mole fraction of solvent = moles of solvent / (moles of solvent + moles of solute)

    by substitute:

    ∴ 0.808 = 0.115 / (0.115 + X)

    So X (the no. of moles of NaCl) = 0.027 m
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