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3 March, 10:18

What partial pressure of hydrogen gas is required in order for 0.00100 g of the gas to dissolve in 17.6 ml of pure water? the henry's law constant for hydrogen gas is 7.8 * 10-4 m atm-1?

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  1. 3 March, 11:43
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    There is a minor typo in this question. The value of 7.8x10^-4 m/atm is nonsense. However, looking up the Henry's constant for hydrogen gas, there is a value of 7.8x10^-4 m / (L*atm) which I will assume is the correct unit and the rest of the problem will be done with that in mind.

    First, determine what the molar concentration would be for 0.00100 g of H2 dissolved in 17.6 ml of water. Start with the atomic weight of hydrogen = 1.00794 g/mol. Molar mass of H2 is twice that, so 2 * 1.00794 = 2.01588 g/mol. So the number of moles of H2 we have is 0.001 g / 2.01588 g/mol = 0.000496061 mol. Finally, the molarity of the solution is 0.000496061 mol / 0.0176 L = 0.0281853 mol/L.

    Now we can use the equation

    Hcp = Ca/p

    where

    Hcp = Henry's constant

    Ca = Concentration in aqueous solution

    p = pressure

    So solve for p, substitute the known values, and calculate:

    Hcp = Ca/p

    p*Hcp = Ca

    p = Ca/Hcp

    p = (0.0281853 mol/L) / (7.8x10^-4 mol / (L*atm))

    p = 36.135 atm

    Rounding to 3 significant figures gives p = 36.1 atmospheres.
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