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31 October, 23:03

The ksp of zinc carbonate (znco3 is 1.0 * 10-10. what is the solubility concentration of carbonate ions in a saturated solution at 25°c? 1.4 * 10-5m 7.1 * 10-6m 1.7 * 10-5m 1.0 * 10-5m

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  1. 1 November, 00:48
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    Answer is: 1.0 * 10-5m.

    Chemical reaction: ZnCO ₃ (s) ⇄ Zn²⁺ (aq) + CO₃²⁻ (aq).

    [Zn²⁺] = [CO₃²⁻] = x; equilibrium concentration of zinc cation and carbonate anion.

    Ksp = [Zn²⁺] · [CO₃²⁻ ].

    1 ·10⁻¹⁰ = x².

    x = [CO₃²⁻] = √1·10⁻¹⁰.

    [CO₃²⁻] = 1·10⁻⁵ M.
  2. 1 November, 01:21
    0
    Ksp - solubility product constant is equivalent to equilibrium constant, except this constant is used to determine the solubility of ions of a solid in a solution.

    ksp is the product of the soluble ions in the compound. Higher the ksp value, higher the degree of solubility.

    ZnCO₃ (s) - - - > Zn²⁺ (aq) + CO₃²⁻ (aq)

    n n

    ksp = [Zn²⁺][CO₃²⁻]

    In the equation equal amounts of ions Zn²⁺ and CO₃²⁻ ions are soluble.

    amount of ions soluble = n

    ksp is therefore equal to;

    ksp = n x n

    ksp = n²

    ksp = 1 * 10⁻¹⁰ M

    therefore

    1 * 10⁻¹⁰ M = n²

    n = 1 x 10⁻⁵ M

    therefore concentration of CO₃²⁻ = 1 x 10⁻⁵ M
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