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10 October, 10:56

how many mL 2.3 M HCl is required to neutralize 85 g of KOH given the balanced reaction HCl + KOH → KCl + H2O? (molar masses: KOH = 56.1 g/mol; HCl = 36.45 g/mol)

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  1. 10 October, 12:05
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    0.66 mL are required for this neutralization

    Explanation:

    This is the neutralization equation

    HCl + KOH → KCl + H₂O

    When you neutralize, you make water like this:

    HCl + H₂O → H₃O⁺ + Cl⁻

    KOH → K⁺ + OH⁻

    H₃O⁺ + OH⁻ ⇄ 2H₂O

    Every time you neutralize, you have to apply this formula:

    Nᵃ. Vᵃ = Nᵇ. Vᵇ

    where N is normality and V volume

    We also know that N. V = Gram equivalent

    and N = M. valence

    where in a base, valence means the quantity of OH inside the formula, and in an acid, valence means the quantity of H

    In HCl, valence is 1 : in KOH is also 1

    Gram equivalent is equal to mass in grams numerically equal to equivalent weight, where the equivalent weight (E) is the molar mass/valence

    So 2.3. Vᵃ = Nᵇ. Vᵇ

    Vᵃ is our unknown.

    So for the base, the Nᵇ. Vᵇ = gram-equivalent

    Gram equivalent = Mass / E

    E = molar mass / valence

    Gram equivalent KOH = 85g / (56.1 g/m / 1)

    Gram equivalent KOH = 1.51

    2.3. Vᵃ = 1.51

    Vᵃ = 1.51 / 2.3 = 0.66 mL
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