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29 April, 19:50

If, at a given temperature, the equilibrium constant for the reaction H2 (g) Cl2 (g) 2HCl (g) is Kp, then the equilibrium constant for the reaction HCl (g) (1/2) H2 (g) (1/2) Cl2 (g) can be represented as:

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  1. 29 April, 20:07
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    Kp = [ (PH2/P°) ∧ (1/2) eq]*[ (PCl2/P°) ∧ (1/2) eq] / (PHCl (g) / P°) eq

    Explanation:

    H2 (g) + Cl2 (g) → 2HCl (g)

    ∴ Kp = F (T)

    ⇒ Kp = (PHCl/P°) eq / [ (PCl2/P°) eq]*[ (PH2/P°) eq]

    ∴ P° = 1 bar

    HCl (g) → (1/2) H2 (g) + (1/2) Cl2 (g)

    ⇒ Kp = [ (PH2/P°) ∧ (1/2) eq]*[ (PCl2/P°) ∧ (1/2) eq] / (PHCl (g) / P°) eq
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