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9 May, 11:34

In the tetrachloromethane (carbon tetrachloride) molecule the Cl-C-Cl bond angle is 109.5º. Which distribution of electrons around the central atom provides the best explanation for this bond angle?

3 shared pairs, 1 lone pair

4 shared pairs

2 shared pairs, 2 lone pairs

1 shared pair, 3 lone pairs

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Answers (1)
  1. 9 May, 14:19
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    4 shared pairs

    Explanation:

    According to the VESPR, a molecule with a central atom C linked to 4 Cl would form a tetrahedral, whose angles are 109.5°. When more lone pairs are added, the repulsion is greater due to the unshared electrons leading to a distorted tetrahedral. The more lone pairs, the lower the bond angle.
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