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31 August, 09:47

Reaction A and reaction B have identical frequency factors. However, reaction B has a higher activation energy than reaction A. Part A Which reaction has a smaller rate constant at room temperature?

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  1. 31 August, 13:46
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    reaction B

    Explanation:

    From Arrhenius equation

    k=A e-Ea/RT

    Where

    K = rate constant

    Ea = activation energy

    R = universal gas constant

    T = temperature in kelvin

    A = frequency factor

    The higher the activation energy, the lower the value of e-Ea/RT. If A is constant for reaction A and B, then the reaction with lower activation energy will have a higher value of rate constant, k because e-Ea/RT will have a higher value. Hence reaction B having a greater activation energy will have a smaller value of rate constant k.
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