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23 June, 21:02

A student prepared asprin in a lab experiment using the reaction that asprin (C9H8O4) is synthesized by reacting salicylic acid (C7H6O3) with acetic anhydride (C4H6O3). The Student reacted 1.50 g salicylic acid with 2.00 g acetic anhydride. The yield was 1.50 g aspring. Calculate the theoretical yield and the percent yield for this experiment.

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  1. 23 June, 22:37
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    The theoretical yield is 1.96 grams of aspirin. The % yield is 76.5%

    Explanation:

    Step 1: Data given

    Mass of salicylic acid (C7H6O3) = 1.50 grams

    Mass of acetic anhydride (C4H6O3) = 2.00 grams

    Yield of aspirin = 1.50 grams

    Molar mass of salicylic acid = 138.12 g/mol

    Molar mass of acetic anhydride = 102.09 g/mol

    Step 2: The balanced equation

    C4H6O3 + C7H6O3 → C9H8O4 + C2H4O2

    Step 3: Calculate moles of C7H6O3

    Moles C7H6O3 = Mass C7H6O3 / molar mass C7H6O3

    Moles C7H6O3 = 1.50 grams / 138.12 g/mol

    Moles C7H6O3 = 0.0109 moles

    Step 4: Calculate moles of C4H6O3

    Moles C4H6O3 = 2.00 grams / 102.09 g/mol

    Moles C4H6O3 = 0.0196 moles

    Step 5: Calculate the limiting reactant

    salicylic acid has the smallest amount of moles, so it's the limiting reactant.

    It will completely be consumed.

    Acetic anhydride is in excess. There will be consumed 0.0109 moles

    There will remain 0.0196 - 0.0109 = 0.0087 moles

    Step 6: Calculate moles of aspirin

    For 1 mol of salicylic acid, we need 1 mol of acetic anhydride to produce 1 mol aspirin

    For 0.0109 moles of salicylic acid we have 0.0109 moles of aspirin

    Step 7: Calculate mass of aspirin

    Mass aspirin = 0.0109 moles * 180.158 g/mol

    Mass aspirin = 1.96 grams ( = theoretical yield)

    Step 8: Calculate % yield

    % yield = actual yield / theoretical yield

    % yield = (1.50 grams / 1.96 grams) * 100%

    % yield = 76.5 %

    The theoretical yield is 1.96 grams of aspirin. The % yield is 76.5%
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