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23 September, 10:27

How would you arrange the following elements in order of increasing ionization energy: Te, Pb, Cl, S, Sn?

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  1. 23 September, 10:32
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    Sn < Pb < Te < S < Cl

    Explanation:

    The ionization energy increases across a period but decreases down a group.

    This means that the elements with the lowest ionization energies would be in the bottom left-hand corner of the periodic table.

    The change in ionization energies is also bigger going down the periodic table than going across the periodic table.

    P b is the element that is in the lowest period at 6 (and lowest group at 14) in the periodic table; it should have the smallest ionization energy.

    In period 5 we have the elements Sn and Te.

    Since ionization energy increases across a period, Sn will have a smaller ionization energy than Te.

    The third period, where we have S and C l.

    Since S is before C l. So it has a lower ionization energy than Cl

    The order (increasing) is: Pb < Sn
    BUT

    The electron configuration of Sn is 5s 2 4d 10 5p 2

    The electron configuration of Pb is 6s 2 4f 14 5d 10 6p 2.

    The 4f electrons in Pb are poor at shielding the outermost electrons.

    So, the outer electrons experience a greater effective nuclear charge, what makes it more difficult to remove them.

    So this means Pb has a higher ionization than Sn

    So the correct order is Sn < Pb < Te < S < Cl

    .
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