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20 March, 12:46

Write the net ionic equation for the acid-base hydrolysis equilibrium that is established when ammonium bromide is dissolved in water. (Use H3O instead of H.) H2O (l) This solution is ___.

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  1. 20 March, 13:39
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    NH₄⁺ (aq) + H₂O (l) ⇄ H₃O⁺ (aq) + NH₃ (aq)

    The solution is acid.

    Explanation:

    Ammonium bromide → NH₄Br

    This is a salt that can dissociates like this:

    NH₄Br (aq) → NH₄⁺ (aq) + Br⁻ (aq)

    NH₄⁺ cation comes from a weak base, the ammonia. So the cation is the conjugate strong acid.

    Br⁻ anion comes from a strong acid (HBr), so the anion is the conjugate weak base and in water, it does not make hydrolisis. It does not react.

    So the NH₄⁺ is the one that can react to water, realeasing one proton as this equation shows:

    NH₄⁺ (aq) + H₂O (l) ⇄ H₃O⁺ (aq) + NH₃ (aq)

    As we give hyrdronium in the medium, the solution is acid.
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