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18 October, 05:17

Nitrogen oxide racts with bromine to form nitrosyl bromide. A sample of 0.0655 mol NO with 0.0328 mol Br2 gives an equilibrium mixture containing 0.0389 mol NOBr. What is the composition of the equilibrum mixture?

2NO (g) + Br2 (g) / leftrightarrow 2NOBr (g)

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  1. 18 October, 08:44
    0
    NO = 0.0265 mol

    Br₂ = 0.0133 mol

    NOBr = 0.0389 mol

    Explanation:

    Let's consider the following reaction.

    2 NO (g) + Br₂ (g) ⇄ 2 NOBr (g)

    We can find the composition at equilibrium using an ICE chart. Let x be an unknow amount.

    2 NO (g) + Br₂ (g) ⇄ 2 NOBr (g)

    I 0.0655 0.0328 0

    C - 2x - x + 2x

    E 0.0655 - 2x 0.0328 - x 2x

    At equilibrium, the mixture contains 0.0389 mol NOBr. Then,

    0.0389 mol = 2x

    x = 0.0195 mol

    The composition of the equilibrium mixture is:

    NO = 0.0655 - 2x = 0.0265 mol

    Br₂ = 0.0328 - x = 0.0133 mol

    NOBr = 0.0389 mol
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