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13 March, 13:28

Suppose that, in a given reaction, the enthalpy (H) increases by 10 units, and the disorder (TS) increases by 12 units. By how many units did the Gibbs free energy change? When I did the calculation it came out to 2 units but the answer is - 2 units. Why is that? Also, is T (delta) S treated as one single unit or separate?

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  1. 13 March, 16:23
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    -2

    Explanation:

    Gibbs free energy is defined by enthalpy of the system minus the product of the temperature and entropy and represented by the formula below:

    G = H - TS where G = Gibbs free energy, H = enthalpy and T = temperature and S = entropy

    change in entropy is defined by the formula below

    ΔG = ΔH - Δ (TS) if the temperature is not constant, but if the temperature is constant then

    ΔG = ΔH - TΔS

    in according to the question (TS) is treated together.

    to the solution

    increase in H = 10 units, increase in the product of temperature and entropy = 12 units

    ΔG = 10 - 12 = - 2
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