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25 July, 14:21

HClO4 acid solution has a concentration of 5 Molarity. Calculate the concentration of this solution in

1. Percentage by weight

2. Molar fractions

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Answers (1)
  1. 25 July, 17:59
    0
    1. Percentage by weight = 0.5023 = 50.23 %

    2. molar fraction = 0.153

    Explanation:

    We know that

    Molar mass of HClO4 = 100.46 g/mol

    So the mass of 5 Moles = 5 x 100.46

    Mass (m) = 5 x 100.46 = 502.3 g

    Lets assume that aqueous solution of HClO4 and the density of solution is equal to density of water.

    Given that concentration HClO4 is 5 M it means that it have 5 moles of HClO4 in 1000 ml.

    We know that

    Mass = density x volume

    Mass of 1000 ml solution = 1 x 1000 = 1000 (density = 1 gm/ml)

    m'=1000 g

    1.

    Percentage by weight = 502.3 / 1000

    Percentage by weight = 0.5023 = 50.23 %

    2.

    We know that

    molar mass of water = 18 g/mol

    mass of water in 1000 ml = 1000 - 502.3 g=497.9 g

    So moles of water = 497.7 / 18 mole

    moles of water = 27.65 moles

    So molar fraction = 5 / (5+27.65)

    molar fraction = 0.153
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