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4 September, 04:56

Calculate the solubility at 25°C of CuBr in pure water and in a 0.0120M CoBr2 solution. You'll find Ksp data in the ALEKS Data tab. Round both of your answers to 2 significant digits. solubility in pure water: * 7.210-4gL solubility in 0.0120 M CoBr2 solution: * 5.210-7gL

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  1. 4 September, 07:04
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    S = 7.9 * 10⁻⁵ M

    S' = 2.6 * 10⁻⁷ M

    Explanation:

    To calculate the solubility of CuBr in pure water (S) we will use an ICE Chart. We identify 3 stages (Initial-Change-Equilibrium) and complete each row with the concentration or change in concentration. Let's consider the solution of CuBr.

    CuBr (s) ⇄ Cu⁺ (aq) + Br⁻ (aq)

    I 0 0

    C + S + S

    E S S

    The solubility product (Ksp) is:

    Ksp = 6.27 * 10⁻⁹ = [Cu⁺].[Br⁻] = S²

    S = 7.9 * 10⁻⁵ M

    Solubility in 0.0120 M CoBr₂ (S')

    First, we will consider the ionization of CoBr₂, a strong electrolyte.

    CoBr₂ (aq) → Co²⁺ (aq) + 2 Br⁻ (aq)

    1 mole of CoBr₂ produces 2 moles of Br⁻. Then, the concentration of Br⁻ will be 2 * 0.0120 M = 0.0240 M.

    Then,

    CuBr (s) ⇄ Cu⁺ (aq) + Br⁻ (aq)

    I 0 0.0240

    C + S' + S'

    E S' 0.0240 + S'

    Ksp = 6.27 * 10⁻⁹ = [Cu⁺].[Br⁻] = S'. (0.0240 + S')

    In the term (0.0240 + S'), S' is very small so we can neglect it to simplify the calculations.

    S' = 2.6 * 10⁻⁷ M
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