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5 June, 08:36

A. Consider four different samples: aqueous LiI, molten LiI, aqueous AgI, and molten AgI. Current run through each sample produces one of the following products at the cathode: solid lithium, solid silver, or hydrogen gas. Match each sample to its cathodic product. B. Consider four different samples: aqueous NaBr, molten NaBr, aqueous NaF, and molten NaF. Current run through each sample produces one of the following products at the anode: liquid bromine, fluorine gas, or oxygen gas. Match each sample to its anodic product.

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  1. 5 June, 09:39
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    At the cathode

    In case of molten AgI

    Silver will be collected

    In case of molten LiI

    lithium will be collected

    in case of aqueous LiI,

    hydrogen gas will be collected as reduction potential of H⁺ is more than Li⁺

    in case of aqueous AgI,

    Silver will be obtained at cathode because reduction potential of silver is more than H⁺

    At the Anode

    In case of molten NaBr

    Bromine will be collected

    In case of molten NaF

    Fluorine will be collected

    in case of aqueous NaBr,

    Bromine will be collected as reduction potential of Br⁻ is less than O⁻²

    in case of aqueous NaF,

    oxygen will be obtained because reduction potential of F⁻ is more than O⁻².
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