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5 September, 10:22

A gas sample containing 1.45 mol at 25°C exerts a pressure of 408 torr. Some gas is added to the same container, and the temperature is increased to 50.°C. If the pressure increases to 800. torr, how many moles of gas were added to the container? Assume a constant-volume container.

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  1. 5 September, 10:46
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    It were added 1.17 moles of gas

    Explanation:

    We use the Ideal Gases Law to propose both situations:

    P. V = n. R. T

    For initial situation → P₁. V₁ = n₁. R. T₁

    For the second situation → P₂. V₂ = n₂. R. T₂

    R is a constant and V remains constant, so we cancel from the equations.

    (n₁. T₁) / P₁ = (n₂. T₂) / P₂

    Notice that n₂ = n₁ + x where n₁ = 1.45 moles.

    Let's make the conversions for the units

    25°C + 273 = 298 K (T₁) and 50°C + 273 = 323K (T₂)

    408 Torr. 1 atm / 760 Torr = 0.537 atm (P₁)

    800 Torr. 1 atm / 760 Torr = 1.05 atm (P₂)

    Let's replace and find the x

    (1.45 mol. 298K) / 0.537 atm = ((x + 1.45mol). 323K) / 1.05 atm

    (1.45 mol. 298K) / 0.537 atm. 1.05 atm = (x + 1.45mol). 323K

    845 mol. K = 323 x K + 468.35 mol. K

    845 mol. K - 468.35 mol. K = 323 x K

    376.65 mol. K / 323 K = x

    1.17 mol = x
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