Ask Question
3 August, 20:29

How to distinguish a solution of sodium sulphite from a solution of sodium sulphate in the lab

+1
Answers (1)
  1. 3 August, 20:59
    0
    We have to distinguish a solution of sodium sulphite from a solution of sodium sulphate in the laboratory.

    Solution of sodium sulphite is acidified with dilute HCl and to that when few drops of barium chloride (BaCl₂) solution is added, white precipitate is formed. The white precipitate is soluble in HCl.

    To this solution 2 drops of iodine (I₂) solution is added and brown colour of iodine is discharged as I₂ gets reduced to HI.

    The reactions involved in case of sodium sulphite is are:

    Na₂SO₃ + BaCl₂ = BaSO₃ ↓ + 2NaCl

    (white precipitate)

    BaSO₃ + 2HCl = BaCl₂ + H₂SO₃

    H₂SO₃ + I₂ + H₂O = H₂SO₄ + 2HI

    On the other hand, solution of sodium sulphate is acidified with dilute HCl and to that when few drops of barium chloride (BaCl₂) solution is added, white precipitate is formed. The white precipitate of BaSO₄ is formed which is insoluble in HCl.

    Na₂SO₄ + BaCl₂ = BaSO₄ ↓ + 2NaCl

    (white precipitate)
Know the Answer?
Not Sure About the Answer?
Find an answer to your question ✅ “How to distinguish a solution of sodium sulphite from a solution of sodium sulphate in the lab ...” in 📘 Chemistry if you're in doubt about the correctness of the answers or there's no answer, then try to use the smart search and find answers to the similar questions.
Search for Other Answers