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15 July, 07:55

Consider the reaction of 2-chloro-2-methylpentane with sodium iodide. Assuming no other changes, how would it affect the rate if one simultaneously doubled the concentration of 2-chloro-2-methylpentane and sodium iodide? Group of answer choices

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  1. 15 July, 11:51
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    The given question is incomplete, the complete question is:

    Consider the reaction of 2-chloro-2-methylpentane with sodium iodide. Assuming no other changes, how would it affect the rate if one simultaneously doubled the concentration of 2 - chloro-2-methylpentane and sodium iodide? + NaCI + Nal CI A) no effect B) it would double the rate C) it would triple the rate D) it would quadruple the rate E) it would increase the rate 5 times

    Answer:

    The correct answer is option B, that is, it would double the rate.

    Explanation:

    Based on the given reaction, the reactant, that is, 2-chloro-2-methylpentane is a sterically crowded molecule, therefore, the formation of the product will take place by SN₁ reaction mechanism. The formation of carbocation takes place in the initial step and is considered as the rate-determining step.

    The rate equation is R = K₁ [A]ⁿ

    Here A is 2-chloro-2-methylpentane, therefore, if the concentration of A increases, the rate of the reaction will get double. Now the rate becomes, R = K₁ [A]²

    In the given case, NaI or sodium iodide is a nucleophile, and the concentration of nucleophile is not present in the rate equation, it is a unimolecular reaction. So, option 1 cannot be correct.
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