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30 December, 18:19

A mixture of 10 moles of A, 5 moles of B and 15 moles of C is placed in a one liter container at a constant temperature. The reaction is allowed to reach equilibrium. At equilibrium the number of moles of B is 9. Calculate the equilibrium constant for the reaction.

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  1. 30 December, 19:01
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    Equilibrium constant is 0.0873

    Explanation:

    For the reaction:

    A + B ⇄ C

    Equilibrium constant is defined as:

    K = [C] / [A] [B]

    concentrations in equilibrium of each reactant are:

    [A] = 10 - X

    [B] = 5 - X

    [C] = 15 + X

    If concentration in equilibrium of B is 9, X is:

    [B] = 5 - X = 9 → X = - 4

    Replacing:

    [A] = 10 - (-4) = 14

    [B] = 5 - (-4) = 9

    [C] = 15 + (-4) = 11

    K = 11 / (14*9) = 0.0873

    Thus, equilibrium constant is 0.0873
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