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18 January, 09:41

Arrange the complexes in order of decreasing stability. Rank from most stable to least stable. To rank items as equivalent, overlap them. [Ni (en) (H2O) 4] [FeF6] [Fe (NH3) 6] [Ni (en) 3])

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  1. 18 January, 10:42
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    Answer: [Ni (en) 3] > [Ni (en) (H2O) 4] > [Fe (NH3) 6] > [FeF6]

    Explanation:

    Generally chelating ligands stabilize the complex more than non chelated ligands and more the no of chelated ligands more the stability.

    Here en (ethylenediamine) is a chelated ligand and stabilze the complex more by chelation.

    And Strong field ligand (NH3) also stabilze the complex more than weak field ligand (F).

    Hence F containing complex is least stable.
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