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29 March, 18:42

How many milliliter of a 0.206M HI solution are needed to reduce 22.5 mL of a 0.374 M KMnO4 solution according to the following equation

10HI+2KMNO4+3H2SO4 - 5I2 + 2MnSO4+8H2O

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  1. 29 March, 19:58
    0
    204mL

    Explanation:

    We'll begin by calculating the number of mole of KMnO4 in 22.5 mL of 0.374 M KMnO4. This is illustrated below:

    Molarity of KMnO4 = 0.374 M

    Volume = 22.5 mL = 22.5/1000 = 2.25x10^-2L

    Mole = ?

    Molarity = mole / Volume

    Mole = Molarity x Volume

    Mole of KMnO4 = 0.374x2.25x10^-2

    Mole of KMnO4 = 8.415x10^-3 mole

    The equation for the reaction is given below:

    10HI + 2KMnO4 + 3H2SO4 - > 5I2 + K2SO4 + 2MnSO4 + 8H2O

    From the balanced equation above,

    2 moles of KMnO4 reacted with 10 moles of HI.

    Therefore, 8.415x10^-3 mole of KMnO4 will react with = (10x8.415x10^-3) / 2 = 0.0421 mole of HI.

    Now, with this amount (i. e 0.0421 mole) of HI, we can obtain the volume of 0.206M HI solution needed for the reaction. This is illustrated below:

    Molarity of HI = 0.206M

    Mole of HI = 0.0421 mole

    Volume = ?

    Molarity = mole / Volume

    Volume = mole/Molarity

    Volume = 0.0421/0.206

    Volume = 0.204L

    Now let us convert 0.204L to mL. This is illustrated below:

    1L = 1000mL

    0.204L = 0.204 x 1000 = 204mL

    Therefore, 204mL of 0.206M HI solution is needed for the reaction.
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