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12 September, 00:09

In which of the following aqueous solutions would you expect AgCl to have the greatest solubility? Why?

A) 0.015M NaCl

B) 0.020M KCl

C) 0.020M BaCl₂

D) 0.020M AgNO₃

E) pure water

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  1. 12 September, 00:16
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    E) pure water.

    Explanation:

    AgCl is a sparingly soluble salt in water which is dissociates according to the reaction:

    AgCl ⇄ Ag⁺ + Cl⁻.

    Adding NaCl, KCl, BaCl₂, and AgNO₃ will shift the equilibrium to the left according to Le Chatelier's principle that the presence of these salts will increase the concentration of Cl⁻ (NaCl, KCl, BaCl₂) or increase the concentration of Ag⁺ (AgNO₃), so the reaction is shifted towards the reactants side decreasing the solubility of AgCl.

    So, the greatest solubility of AgCl will be in pure water.
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