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29 August, 23:24

Which stereoisomer - cis - or trans-1-bromo-3-tert-butylcyclohexane - will react faster in an E2 elimination reaction? Select the single best answer.

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  1. 30 August, 01:42
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    Cis-1-bromo-3-tert-butylcyclohexane will give faster reaction in E2 elimination.

    Explanation:

    E2 is known as second order reaction. Such reaction take place in a single step. E2 involve breaking of C-H and C-X bond in order to form double bond.

    Role of cis geometry:

    The base mostly remove hydrogen which is anti-palanar to halogen. So when both group i. e bromide and tert-butyl group will be on one side, (cis), then base can abstract hydrogen easily as a result double bond formation take place so fastly.
  2. 30 August, 02:09
    0
    The cis molecule will react faster.

    Explanation:

    In the E2 mechanism, we have to have an anti-peri-planar configuration. The hydrogen that is removed and the leaving group should have a configuration of 90º in an anti position (see the figure red hydrogens).

    In the trans configuration the ter-butyl group would exercise a steric hindrance upon the hydrogens that can be removed. In the cis configuration we don't have this problem. Therefore the cis molecule would react faster.
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