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25 March, 08:33

What is electrolysis in a formula?

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Answers (2)
  1. 25 March, 09:53
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    Relative atomic masses needed: Na = 23, Cl = 35.5, H = 1, Cu = 63.5, Al = 27, O = 16 and the molar volume of any gas is 24 dm3 at room temperature and pressure. The common electrode equations you may come across are listed below.

    electrode involved: (-) negative cathode or (+) positive anode for the Electrode Equation below

    moles of electrons involved (mass of product formed)

    example of industrial process where this electrode reaction happens

    sodium (-) Na + (l) + e - = = > Na (l)

    1 (23g) = 1.0 mol Na metal per mol e-s

    electrolysis of molten chloride salts to make chlorine and the metal

    chlorine (+) 2Cl - (l/aq) - 2e - = = > Cl2 (g)

    2 (71g) = 0.5 mol Cl2 gas (12 dm3) released per mol e-s

    electrolysis of molten chloride salts or their aqueous solution to make chlorine

    hydrogen (-) 2H + (aq) + 2e - = = > H2 (g)

    2 (2g) = 0.5 mol H2 gas (12 dm3) released per mol e-s

    electrolysis of many salt solutions to make hydrogen

    copper (-) Cu2 + (aq) + 2e - = = > Cu (s)

    2 (63.5g) = 0.5 mol Cu deposited per mol e-s

    deposition of copper in its electrolytic purification or electroplating

    copper (+) Cu (s) - 2e - = = > Cu2 + (aq)

    2 (63.5g) = 0.5 mol Cu dissolves per mol e-s

    dissolving of copper in its electrolytic purification or electroplating

    aluminium (-) Al3 + (l) + 3e - = = > Al (l)

    3 (27g) = 0.33 mol Al metal per mol e-s

    extraction of aluminium in the electrolysis of its molten oxide ore

    oxygen (+) 2O2 - (l) - 4e - = = > O2 (g)

    4 (32g) = 0.25 mol O2 (12 dm3) gas released per mol e-s electrolysis of molten oxides

    oxygen (+) 4OH - (aq) - 4e - = = > 2H2O (l) + O2 (g)

    4 (32g) = 0.25 mol O2 gas (6 dm3) released per mol e-s electrolysis of many salt solutions such as sulphates, sulphuric acid etc. gives oxygen (but chloride salts = = > chlorine)

    (Thats some formulas for different elements that are commenly used)
  2. 25 March, 11:51
    0
    2H2O (I) - - - >2H2 (g) + O2 (g)
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