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27 November, 06:59

When might a plot of ln[a] vs time not yield a straight line?

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  1. 27 November, 09:17
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    Considering a reaction:

    A → B

    The rate equation may be described as:

    r = - k[A]ⁿ

    Taking the natural log,

    ln (r) = - nln ([A]) + ln (k)

    Therefore, the only time the graph of ln[A] vs time will be a straight line is when the order of the reaction is 0, meaning the reaction is independent of reactant concentration.
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