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14 June, 09:07

A 8.048 gram sample of an organic compound containing C, H and O is analyzed by combustion analysis and 12.00 grams of CO2 and 3.684 grams of H2O are produced.

In a separate experiment, the molar mass is found to be 118.1 g/mol. Determine the empirical formula and the molecular formula of the organic compound.

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  1. 14 June, 11:53
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    Procedure: The first set of data are use to determine the empirical formula, then the molar mass is used to detemine the molar mass.

    1) Quantity of each elements

    C: it is only present in CO2.

    The ratios of each element in CO2 are: 1 atom C / 2 atom O or, using the atomic masses, 12 g C / 32 g O

    Then in 12.00 g of CO2 there are: [12 g C / 44 g CO2] * 12.00 g CO2 = 3.2727 g C

    The ratios of each element in H2O are: 2 atom H / 1 atom O or, using the atomic mass, 2 g H / 16 g O

    Then in 3.684 g of water there are: [2 g H / 18 g H2O] * 3.684 g H2O = 0.4093 g H

    Then the original sample had 8.048 g of Sample - 3.2727 g of C - 0.4093 g of H = 4.366 g of O

    2) Now, convert he masses of each element into moles, using the atomic mass of each element

    C: 3.2727 g / 12.0 g/mol = 0.2727 mol

    H: 4.093 g / 1.0 g/mol = 0.4093 mol

    O: 4.366 / 16.0 g/mol = 0.2729 mol

    3) Now divide by the smallest number (0.2727) to find the proportion of the elements

    C: 0.2727 / 0.2727 = 1.0

    H: 0.4093 / 0.2727 = 1.5

    O: 0.2729 / 0.2727 = 1.0

    Given the the number of mols of H is 1.5 multiply all the numbers by 2 to obtain integer numbers = >

    C: 2

    H: 3

    O: 2

    Then, the empirical formula is C2 H3 O2

    4) Find the mass of the empirical formula

    C: 2 mol * 12.00 g/mol = 24 g

    H: 3 mol * 1 g / mol = 3 g

    O: 2 mol * 16 g / mol = 32 g

    Total mass: 24g + 3g + 32 g = 59 g

    5) Finally find the number of times that this mass (59g) is contained in the molar mass (118.1 g) = 118.1 / 59 = 2.00

    This is the number for which you have to multiply all the subscripts of the empirical formula to get the molecular formula = >

    Then, the molecular formula is C4 H6 O4
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