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4 December, 18:07

What is the value of kc for the decomposition of hi at 623 k?

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  1. 4 December, 20:14
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    I2 + 2Na2 (S2O3) → Na2 (S4O6) + 2NaI

    (28.68ml) (0.015 mmol/ml) = 0.4303 mmol [S2O3]2 - consumed

    Therefore, there were 0.4303/2 mmol = 0.2151 mmol I2 present

    initial 0.280g HI = 280mg / (127.91 mg/mmol) = 2.189 mmol

    ... 2HI (g) ⇌ H2 (g) + I2 (g)

    2.189-2x ... x ... x

    Therefore, final HI = 2.189 - 2 (0.2151) mmol

    Kc = (0.2151) ^2 / (2.189 - 2 (0.2151)) ^2 = 0.01496

    Because the # of moles of reactants and products are equal, the volume of the bulb isn't needed (it cancels out of Kc). For the same reason Kc = Kp
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