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15 May, 08:18

The chirping of tree crickets has sometimes been used to predict temperatures. at 25.0 °c, the rate was 179 chirps/min. at 21.7 °c, it was 142 chirps/min. what is the ea of the process?

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  1. 15 May, 09:41
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    The relation of the rate, K, the activation energy, Ea, and the absolute temperature, T, is given by Arrhenius equation.

    Arrhenius equation is:

    K (T) = A * e^ (-Ea / RT)

    Then A is a constant for the specific reaction and R is the universal constant of gases.

    Then you can use two set of values, at different T, to find Ea

    1) K = 179 chirp/min; T = 25 + 273 = 298 K

    2) K = 142 chirp/min; T = 21.7 + 273 = 294.7 K

    =>

    179 = A * [ e ^ (-Ea / R*298) ]

    142 = A * [e^ (-Ea / R * 294.7) ]

    Divide thw two equations:

    [179 / 142 ] = e ^ [ - (Ea / R) * (1 / 298 - 1 / 294.7) ]

    => - Ea / R = Ln [179/142] / (1 / 298 - 1/294.7)

    => - Ea / R = - 6162.31 K

    The value of the Universal Constant of gases is R = 8.31 J/K*mol

    => Ea = (6162.31 K) * (8.31 J/K*mol) = 51208.81 J/mol

    Answer: 51209 J/mol
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