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14 April, 04:20

A certain buffer is made by dissolving nahco3 and na2co3 in some water. write equations to show how this buffer neutralizes added h and oh.

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  1. 14 April, 07:57
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    - A buffer solution resists the change in pH after the addition of small amounts of acid or base to it.

    - The given buffer solution is NaHCO₃ (acid) + Na₂CO₃ (conjugate base).

    - NaHCO₃ contains HCO₃⁻ and Na⁺ ions. Na₂CO₃ contains Na⁺ and CO₃²⁻ ions. Na⁺ ions do not show any effect on the pH of a solution.

    Therefore, HCO₃⁻ and CO₃²⁻ are responsible for the buffer action.

    HCO₃⁻ is the acidic component of the buffer. It neutralizes the small amounts of base added to it producing an equivalent amount of the conjugate base CO₃²⁻.

    HCO₃⁻ (aq) + OH⁻ (aq) → CO₃²⁻ (aq) + H₂O (l)

    Acid conjugate base

    CO₃²⁻ is the basic component if the buffer. It neutralizes the small amounts of acid added to it producing an equivalent amount of the conjugate acid HCO₃⁻

    CO₃²⁻ (aq) + H₃O⁺ (aq) → HCO₃⁻ (aq) + H₂O (l)

    Base Conjugate acid

    - Therefore, even after the addition of a small amount of acid or base to the buffer, pH remains unchanged.
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