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7 June, 13:53

Determine the molar solubility for pb3 (po4) 2 in pure water. ksp for pb3 (po4) 2 is 1.0 x 10-54.

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  1. 7 June, 14:52
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    Dissociation of Pb₃ (PO₄) ₂ is;

    Pb₃ (PO₄) ₂ (s) ⇆ 3Pb²⁺ (aq) + 2PO₄³⁻ (aq)

    initial - -

    change - X + 3X + 2X

    Equilibrium 3X 2X

    Ksp = [Pb²⁺ (aq) ]³ [PO₄³⁻ (aq) ]²

    1.0 x 10⁻⁵⁴ = (3X) ³ (2X) ²

    1.0 x 10⁻⁵⁴ = 108X⁵

    X = 6.21 x 10⁻¹² M

    Hence the molar solubility of Pb₃ (PO₄) ₂ is 6.21 x 10⁻¹² M.
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