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9 May, 16:35

Calculate the mass of water vapour present in a room of volume 400 m3 that contains air at 27 °C on a day when the relative humidity is 60 per cent. Hint: Relative humidity is the prevailing partial pressure of water vapour expressed as a percentage of the vapour pressure of water vapour at the same temperature (in this case, 35.6 mbar).

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  1. 9 May, 17:36
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    Mass of water = 6251. 706g or 6.25Kg

    Explanation:

    Relative humidity = (actual vapor pressure/saturation vapor pressure) * 100%

    Actual vapor pressure, Pw = relative humidity * saturation vapor pressure

    Pw = 60% * (35.6 * 0.001) atm = 0.0216atm

    Note: 1mbar = 0.001atm

    Using the ideal gas equation: PV=nRT; where P = Pw = 0.02136atm, V = (400

    * 1000) dm^3, R = 0.082 atmdm^3/kmol, T = (27+273) K, n = number of moles

    Note: 1m^3 = 1000dm^3, R is the molar gas constant.

    Making n subject of the formula, n = PV/RT

    n = (0.02136 * 400000) / (0.082 * 300) = 347.317 moles

    Mass (g) = number of moles (n) * molar mass

    molar mass of water=18g

    Mass of water = 347.317 * 18 = 6251. 706g or 6.25Kg
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