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14 June, 17:55

What functional group is expected when hex-3-yne is treated with disiamylborane, followed by treatment with basic hydrogen peroxide? A Ketone B Aldehyde C Diol D Ether

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  1. 14 June, 20:29
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    Ketone.

    Explanation:

    Disiamylborane is used for hydroboration of an alkene or alkyne.

    An alkene hydroboration gives an alcohol and an alkyne gives carbonyl compound.

    A terminal alkyne gives aldehyde while a non terminal alkyne gives ketone or hydroboration.

    The role of hydrogen peroxide is that it results in oxidative hydroboration and hydroboration can also be reductive if we use Zinc.
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