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30 November, 17:32

A certain reaction with an activation energy of 155 kJ/mol was run at 495 K and again at 515 K. What is the ratio of f at the higher temperature to f at the lower temperature

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  1. 30 November, 21:11
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    4.32 is the ratio of f at the higher temperature to f at the lower temperature

    Explanation:

    Using the sum of Arrhenius equation you can obtain:

    ln (f₂/f₁) = Eₐ / R ₓ (1/T₁ - 1/T₂)

    Where f represents the rate constant of the reaction at T₁ and T₂ temperatures. Eₐ is the energy activation (155kJ / mol = 155000J/mol) and R is gas constant (8.314J/molK)

    Replacing:

    ln (f₂/f₁) = 155000J/mol / 8.314J/molK ₓ (1/495K - 1/515)

    Where 2 represents the state with the higher temperature and 1 the lower temperature.

    ln (f₂/f₁) = 155000J/mol / 8.314J/molK ₓ (1/495K - 1/515)

    ln (f₂/f₁) = 1.4626

    f₂/f₁ = 4.32

    4.32 is the ratio of f at the higher temperature to f at the lower temperature
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