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22 January, 11:16

Consider a metal ion with the outer electron configuration of d^4. In a coordination complex, the number of unpaired electrons in that metal ion depends on the orientation and type of ligands that surround it. Classify each description of a complex by the number of unpaired electrons in the d^4 metal ion.

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  1. 22 January, 14:05
    0
    a) 0

    b) 4

    c) 4

    d) 4

    e) 2

    f) 4

    Explanation: No. unpaired electrons:

    a) square planar, strong field

    d⁴ 0

    b) tetrahedral, strong field

    d⁴ 4

    c) Octahedral, weak field

    d⁴ 4

    d) square planar, weak field

    d⁴ 4

    e) Octahedral, strong field

    d⁴ 2

    f) tetrahedral, weak field

    d⁴ 4
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