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25 June, 08:29

Anhydrous CoCl2 is blue; CoCl2•6H2O is red. When CoCl2•6H2O is heated and water is clearly being driven off, it becomes uniformly violet before turning blue. How can this be explained?

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  1. 25 June, 10:01
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    Answer: On losing 6 moles of water, cobalt chloride forms unstable violet-coloured ions, before generating its stable blue-coloured anhydrous form.

    Explanation:

    The hydrated cobalt chloride loses its 6 water of crystallization, then dissociates into ions: cobalt ions and chlorine ions that appear violet, and quickly combined to form the stable anhydrous Cobalt chloride with blue colour.
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