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5 May, 16:40

What is the rate constant of a first-order reaction that takes 143 seconds for the reactant concentration to drop to half of its initial value?

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  1. 5 May, 19:29
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    k = 4.85 x 10⁻³ / s

    Explanation:

    For a first order reaction we have two very important equations we need to memorize:

    ln (N/N₀) = - kt

    and,

    0.693 / k = t₁/₂

    where k is the rate constant and t i is the halflife which can be derived from the first equation.

    0.693 / k = t₁/₂ ⇒ k = 0.693 / t₁/₂

    k = 0.693 / 143 s = 4.85 x 10⁻³ / s
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