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16 December, 23:33

Question 1: Which of the following statement is false about conjugated systems?

A. A conjugated system is more stable than an unconjugated system.

B. The s-trans isomer is favored over the s-cis isomer.

C. A conjugated system has multiple resonance structures.

D. A conjugated system can only contain two alkenes

Question 2: Which statement concerning alkenes is false?

A. A trans alkene releases less heat upon hydrogenation than a cis alkene.

B. A cumulated diene is less stable than an isolated diene.

C. Multiple products can always form when treated a conjugated diene with HBr.

D. Conjugated systems arise only between sp2-hybridized atoms.

E. Conjugated double bonds involve unhybridized p-orbitals aligned with each other

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Answers (1)
  1. 17 December, 00:59
    0
    A conjugated system can only contain two alkenes: False

    B. A cumulated diene is less stable than an isolated diene.

    False

    Explanation:

    A. A conjugated system is more stable than an unconjugated system.: True

    Due to resonance a conjugated system is more stable.

    B. The s-trans isomer is favored over the s-cis isomer.: True

    Due to repulsion in s-cis isomer they are less stable.

    C. A conjugated system has multiple resonance structures. True

    This is the reason they are stable.

    D. A conjugated system can only contain two alkenes: False

    A conjugated system may have may alternate double and triple bonds.

    2) A trans alkene releases less heat upon hydrogenation than a cis alkene.

    True

    Trans alkenes are more stable than cis alkene. Thus heat of hydrogenation of trans alkene is less than cis alkene.

    B. A cumulated diene is less stable than an isolated diene.

    False

    C. Multiple products can always form when treated a conjugated diene with HBr. True

    There can be 1,2 or 1,4 addition

    D. Conjugated systems arise only between sp2-hybridized atoms.

    True

    Conjugation allows resonance which is possible in sp2 systems

    E. Conjugated double bonds involve unhybridized p-orbitals aligned with each other

    True

    The double bond is formed as pi bond due to side ways overlapping of unhybridized p orbitals
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