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21 October, 17:01

A solution of an unknown monoprotic acid was prepared by dissolving 72.9 mg of the acid into 50. mL of water. 10.0 mL of 0.10 M NaOH is needed to titrate a 25 mL aliquot of the unknown monoprotic acid. From this info, calculate the molar mass of the unknown acid (g/mol).

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  1. 21 October, 19:31
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    36.45 g/mol

    Explanation:

    The titration of a monoprotic acid with a base as NaOH is:

    HX + NaOH → NaX + H₂O.

    That means 1 mol of acid reacts per 1 mol of base.

    10.0mL of 0.10M NaOH are:

    0.0100L ₓ (0.10mol / L) = 0.0010 moles NaOH ≡ 0.0010 moles HX

    If 72.9mg of the monoprotic acid are dissolved in 50.0 mL of water, 25 mL of the solution will contains:

    72.9mg * (25mL / 50mL) = 36.45mg = 0.03645g of HX.

    Molar mass is ratio between mass and moles of substance, that is:

    0.03645g of HX / 0.0010 moles HX = 36.45 g/mol
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