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13 September, 06:37

A sample of octane in equilibrium with its vapor in a closed 1.0-L container has a vapor pressure of 50.0 torr at 45°C. The container's volume is increased to 2.0 L at constant temperature and the liquid/vapor equilibrium is reestablished. What is the vapor pressure?

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  1. 13 September, 06:50
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    50 torr

    Explanation:

    Given:

    Initial volume of the octane sample = 1.0 L

    Initial vapor pressure = 50.0 torr

    Increased volume = 2.0 L

    Now, according the condition given in the problem the vapor pressure will be 50 torr for 2.0 L sample

    The vapor pressure is same for the 2.0 L sample because, the temperature is remained constant and the vapor pressure does not depend on the volume of the sample.
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